In this paper a new family of mixed finite volume methods is analyzed for t
he approximation of a reaction-diffusion problem. All the methods are obtai
ned starting from the dual mixed formulation of the problem and then employ
ing the lowest-order Raviart Thomas finite element spaces plus a suitable q
uadrature formula for the mass matrix. This allows for the use of different
averages of the inverse diffusion coefficient to enforce the constitutive
law for the fluxes at the interelement boundary in a finite volume fashion.
The soundness of the methods is supported by an error analysis which shows
optimal O (h) convergence rate with respect to the standard mixed finite e
lement norm in the case of both smooth and piecewise smooth coefficients. N
umerical results on test problems with both smooth and nonsmooth coefficien
ts support the theoretical estimates.