A facile cleavage of ketone N,N-dimethylhydrazones by CeCl3 center dot 7H(2)O-SiO2

Citation
Js. Yadav et al., A facile cleavage of ketone N,N-dimethylhydrazones by CeCl3 center dot 7H(2)O-SiO2, SYNLETT, (7), 2001, pp. 1134-1136
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
7
Year of publication
2001
Pages
1134 - 1136
Database
ISI
SICI code
0936-5214(200107):7<1134:AFCOKN>2.0.ZU;2-V
Abstract
Ketone N,N-dimethylhydrazones are rapidly and chemoselectively deprotected to thr corresponding ketones in high yields by CeCl3. 7H(2)O supported on s ilica gel under microwave irradiation. The method is compatible with acid s ensitive substrates.