Solvent-free chelation-assisted intermolecular hydroacylation: effect of microwave irradiation in the synthesis of ketone from aldehyde and 1-alkene by Rh(I) complex

Authors
Jun, CH Chung, JH Lee, DY Loupy, A Chatti, S
Citation
Ch. Jun et al., Solvent-free chelation-assisted intermolecular hydroacylation: effect of microwave irradiation in the synthesis of ketone from aldehyde and 1-alkene by Rh(I) complex, TETRAHEDR L, 42(29), 2001, pp. 4803-4805
Citations number
19
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
29
Year of publication
2001
Pages
4803 - 4805
Database
ISI
SICI code
0040-4039(20010716)42:29<4803:SCIHEO>2.0.ZU;2-W
Abstract
As a green alternative to classical homogeneous catalyst in toluene in clos ed vessels, the intermolecular hydroacylation of l-alkenes with aldehydes b y Rh(I) complex (Wilkinson catalyst) can be realized efficiently under solv ent-free conditions. When coupled to microwave activation, it results in a serious improvement when compared to classical conditions. (C) 2001 Elsevie r Science Ltd. All rights reserved.