We present a total time series of high signal-to-noise, high-resolution spe
ctra of the SiIII lambda 4552.6, lambda 4567.8 and lambda 4574.8 Angstrom l
ines of the fast-rotating, spectroscopic binary and beta Cephei star kappa
Scorpii. Among this data set is a sample of 422 spectra of intensive monito
ring during eight subsequent nights in July 1997. We find variability of th
e line profiles on two time-scales: a variation of several months as a resu
lt of the orbital motion and rapid variations of a few hours, which are exp
lained in terms of non-radial pulsation modes. From the total dataset, cove
ring a time span of 9 years, we derive for the first time the orbital param
eters of kappa Scorpii and find an orbital period of 195 days. The complex
patterns on the grayscale representations of the residual SiIII lambda 4552
.6 Angstrom profiles with respect to the average profile point towards more
than one (non-axisymmetric) pulsation mode. A frequency analysis of the th
ree normalised velocity moments confirms the main period of 4.80 hours and
the second period of 4.93 hours, which were previously derived from photome
tric data. We attempt an identification of the pulsation modes by means of
the moment method and line-profile fitting and find that kappa Scorpii puls
ates in a main prograde sectoral mode of degree 1 or 2 and in an additional
tesseral mode for which l = 5, m = 1 are the most likely wavenumbers. In t
he variations of the line profiles we find indications for the presence of
additional pulsation modes.