We performed an observational program with the X-ray satellite BeppoSAX, to
study objects with extreme synchrotron peak frequencies (nu (peak) > 1 keV
). Of the seven sources observed, five revealed or confirmed their extreme
nature. Four showed peak frequencies in the range 1-5 keV, while one (1ES 1
426+428) displayed a at power law spectrum (alphax = 0.92 +/-0.04) which lo
cates its synchrotron peak at or above 100 keV. This is the third source of
this type ever found, after Mkn 501 and 1ES 2344+514. In the context of th
e whole blazar class, the broad band properties of these objects confirm th
e scenario of a synchrotron peak smoothly spanning the IR - X-ray range, wh
ich explains the multi-frequency properties of the blazar class. Our data a
lso confirm the large nu (peak) variability which seems to characterize thi
s class of sources, compared with lower nu (peak) objects. Given the high s
ynchrotron peak energies, which ag the presence of high energy electrons, t
hese extreme BL Lacs are also good candidates for TeV emission, and therefo
re good probes of the IR background.