A. Bariteau et M. Thiry, Analysis and simulation of the geochemical transfers within an aquifer: the Beauce ground-water and the alteration of the Fontainebleau Sands, B SOC GEOL, 172(3), 2001, pp. 367-381
Aims. - Ground-water mineralisation results mainly from alteration of the c
onfining aquifer along its flow path. Such alteration may deeply alter the
aquifer formations and have to be recognized to avoid misinterpretation of
the altered facies. The Beauce ground-water and the Fontainebleau Sands aqu
ifer have been studied to highlight such ground-water/aquifer interactions.
The Beauce ground-water is contained in thick limestone series (Oligo-Mioce
ne) interlayered with the Fontainebleau Sands (Stampian). The sands show va
rious facies related to the geomorphology : dark and reduced facies are res
tricted to the bottom of the Formation in the center of the plateaux, oxidi
zed yellowish facies occur in the vadose zone beneath the plateaux, and ble
ached white facies at the edge of the plateaux. These Facies result from mo
dern alterations due to the ground-water and the recharge waters. The water
and rock chemistry allows to investigate the diverse stages of the geochem
ical and weathering processes that occur within the aquifer, and to calcula
te accurate mass balance of the dissolved and exported elements.
Hydrochemistry of the Beauce ground-water. - Each compartment of the aquife
r can be characterised by one type of water. (1) The aquifer is recharged b
y two types of water. The waters coming from the limestone plateau are calc
o-carbonaceous, oxygenated and lightly mineralised, especially in silica :
those coming from the sandy soils near the outcropping sand area are more a
cidic, oxygenated and very lightly mineralised. (2) The ground-water of the
limestone aquifer are oxygenated, oversaturated with respect to quartz and
near equilibrium with calcite and cristobalite. Silica comes from the alte
ration of the clay minerals and/or the cherts in the limestones. The ground
-waters are of calco-carbonaceous type, have pH values approx 6.5. They are
characterised by a relative low mineralisation (average 460 mg.kg(-1)), an
oversaturation with respect to quartz and the presence of dissolved oxygen
(Eh around +450 mV). (3) The ground-water of the dark sands aquifer contai
ns hydrogen sulfur and is oxygen free (Eh around +140 mV), with relatively
high Fe and SO4 contents related to the pyrite oxidation. It is also charac
terised by a relatively high SiO2 and cations contents resulting from the a
lteration of the alumino-silicates. (4) The ground-water of the bleached sa
nds aquifer is strongly diluted by the recharge waters from the sand-v soil
s. It remains oversaturated with respect to quartz and has the ability to h
ydrolyse the alumino-silicates.
Geochemical modelling. - The ground-water/aquifer interactions have been mo
delled. The modelisation takes into account the kinetics of water/rock inte
ractions and was done by successive steps. (1) Alteration of the dark sands
by the ground-water leads to dissolution of the pyrite and the calcite. Th
e pyrite oxidation and the << buffering >> calcite dissolution directly dep
end on oxygen availability in the ground-water. Muscovite remains stable. f
eldspars and glauconite are partially dissolved and Al-smectite forms. The
composition of the resulting simulated oxydized sands agrees with the analy
ses. (2) The leaching of these oxydized sands by the calco-carbonaceous rec
harge water leads to simulate leached sands of similar composition than the
unsaturated sands beneath the plateau. Muscovite remains stable: smectite,
kaolinite and hematite form. (3)The final leaching of the former leached r
and by the acidic recharge water brings about to simulate bleached sand. Th
e muscovite stability, smectite dissolution and kaolinite precipitation are
in conformity with the composition of the white sands.
Nevertheless. the modelisation is not fully in agreement with the mass bala
nce calculations. The discrepancy mainly comes from the simulation of exces
sive amounts of clay minerals and iron oxides. This precipitation excess ma
y be related to the fact that the precipitation kinetics and/or of the orga
nic complexations have not been taken into account in the model. Even if th
eie is discrepancy in the mass balance, the thermokinetic simulations valid
ate the reaction path which leads to the Beauce ground-water mineralisation
and the Fontainebleau Sands bleaching.
Discussion. - Ground-water chemistry thus provides information on the alter
ation processes and indicates that the alte rations are presently active. T
he white facies results from the progressive alteration of dark primary san
ds. This bleaching leads to a complete change of the geochemical characteri
stics of the Fontainebleau Sands. These alterations come with the export of
a large amount of material corresponding to a geochemical lowering of the
Beauce Plateau of at least 10 m during the Plio-Quaternary period.
This example illustrates the importance of the sub-surface alterations due
to ground-water flow, that are difficult to gauge from outcrop observation
only.