H. Cui et al., Effect of photosensitizer riboflavin on the fate of 2,4,6-trinitrotoluene in a freshwater environment, CHEMOSPHERE, 44(4), 2001, pp. 621-625
The effect of riboflavin (1 muM) on the fate of TNT (20 mg/l) in a natural
water environment was studied. The relative contribution of photolysis, mic
robial assemblages and freshwater matrix to TNT degradation was examined. T
he rates, extent and products of TNT and riboflavin transformation were com
pared under different experimental conditions. It was found that riboflavin
significantly enhanced the degradation of TNT in natural water environment
. Thus it is a potentially useful photosensitizing agent for the treatment
of TNT-contaminated surface water. Furthermore, in the presence of riboflav
in, two new intermediates with max, absorption wavelength of 230 nm were fo
und, demonstrating that transformation of TNT in the presence of riboflavin
undergoes different pathways. (C) 2001 Elsevier Science Ltd. All rights re
served.