A new type of oscillating reaction was found from the systematic design of
the chemical oscillator in water in oil (W/O) emulsions. It Is an acidity h
ydrolysis reaction of long chain triglyceride in W/O emulsion at 25.0 +/- 0
.1 degreesC in a bath stirring reactor. During the process of reaction, the
re were periodic and semi-periodic changes lasting more than 10 hours both
in electrolytic conductivity and electric potential. Microscope also reveal
ed that the emulsion structure changed regularly and quickly. Because of th
e large difference in the solubility of the hydrolyzed products, it could b
e thought, that the different redistribution in the two phases of water and
oil induces the regular changes. Marangoni effect of interface membrane ma
de oscillation to form. The oscillating reaction can be used to explain the
periodic change in the living system produced from coupling between reacti
on and diffusion.