Synthesis and NMR spectra of 1,6-anhydro-2,3-dideoxy-2,3-epimino- and 1,6-anhydro-3,4-dideoxy-3,4-epimino-beta-D-hexopyranoses

Authors
Karban, J Budesinsky, M Cerny, M Trnka, T
Citation
J. Karban et al., Synthesis and NMR spectra of 1,6-anhydro-2,3-dideoxy-2,3-epimino- and 1,6-anhydro-3,4-dideoxy-3,4-epimino-beta-D-hexopyranoses, COLL CZECH, 66(5), 2001, pp. 799-819
Citations number
26
Categorie Soggetti
Chemistry
Journal title
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
ISSN journal
00100765 → ACNP
Volume
66
Issue
5
Year of publication
2001
Pages
799 - 819
Database
ISI
SICI code
0010-0765(200105)66:5<799:SANSO1>2.0.ZU;2-9
Abstract
A complete series of 2,3-dideoxy-2,3-epimino- and 3,4-dideoxy-3,4-epimino-1 ,6-anhydro-beta -D-hexopyranoses were prepared by lithium aluminum hydride reduction of the corresponding trans-azido tosylates or trans-azido epoxide s of 1,6-anhydro-beta -D-hyxopyranoses. The structure of the epimino deriva tives was confirmed by H-1 and C-13 NMR spectra.