Synthesis and radical polymerization of novel methacrylates with mesoionic6-oxo-1,6-dihydropyrimidin-3-ium-4-olates as photosensitive components

Authors
Theis, A Ritter, H
Citation
A. Theis et H. Ritter, Synthesis and radical polymerization of novel methacrylates with mesoionic6-oxo-1,6-dihydropyrimidin-3-ium-4-olates as photosensitive components, DES MON POL, 4(2), 2001, pp. 177-194
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
DESIGNED MONOMERS AND POLYMERS
ISSN journal
1385772X → ACNP
Volume
4
Issue
2
Year of publication
2001
Pages
177 - 194
Database
ISI
SICI code
1385-772X(2001)4:2<177:SARPON>2.0.ZU;2-F
Abstract
New polymerizable mesoionic 6-oxo-1,6-dihydropyrimidin-3-ium-4-olates 5a-f have been synthesized using tosylated 2-hydroxymethyl methacrylate and vari ous thioureas and malonic acids. Radical polymerization of the mesoionic de rivatives 5a, c, d, e with AIBN as initiator resulted in soluble polymers. which were used for the preparation of photosensitive films.