We report seismic evidence for a unique 300 km thick layer at the base of t
he mantle beneath the south Atlantic ocean. with a steeply dipping edge. an
omalously low sheer wave velocities linearly decreasing from 2% (top) to 10
-12% (bottom), and a maximum P velocity decrease of 3% relative to the prel
iminary reference Earth model (PREM). These characteristics can be best exp
lained by partial melt driven by a compositional change produced early in t
he Earth's history and a vertical thermal gradient within the lever. This b
oundary layer may provide an explanation for the distinctive isotope geoche
mical DUPAL anomaly observed at some surface ocean islands. (C) 2001 Elsevi
er Science B.V. All rights reserved.