The structures and energetics of carbon bridged C-60 clusters (C-60)(n)C-m
have been studied by simulated annealing technique within the tight-binding
molecular-dynamics. The "sp(2) addition" ball-and-chain dimers exhibit odd
-even alternations: over the number of chain atoms, with the dimers contain
ing even chain atoms more stable against dissociation than their immediate
neighbors containing odd chain atoms. In addition to the usual "sp(2) addit
ion" dimers, a pentagon-linked C-121 isomer and a hexagon-linked C-122 isom
er are also found to be stable. Based on our til:ht-binding: calculations,
trimers and larger clusters: can be simply regarded as: being made lap of i
ndependent or weakly interacting dimers, if the C-C-60 joints on a single c
age are not too close to each other. Large C-60 clusters connected by chain
s each containing only one or two carbon atoms wave similar stability to th
at of constituent dimers, indicating the possibility to form stable C-60-ca
rbon polymers.