Gaussian density fluctuations and mode coupling theory for supercooled liquids

Citation
E. Zaccarelli et al., Gaussian density fluctuations and mode coupling theory for supercooled liquids, EUROPH LETT, 55(2), 2001, pp. 157-163
Citations number
37
Categorie Soggetti
Physics
Journal title
EUROPHYSICS LETTERS
ISSN journal
02955075 → ACNP
Volume
55
Issue
2
Year of publication
2001
Pages
157 - 163
Database
ISI
SICI code
0295-5075(200107)55:2<157:GDFAMC>2.0.ZU;2-O
Abstract
The equations of motion for the density modes of a fluid, derived from Newt ons equations, are written as a linear generalized Langevin equation. The c onstraint imposed by the fluctuation-dissipation theorem is used to derive an exact form for the emory function. The resulting equations, solved under the assumption that the noise, and consequently density fluctuations, of t he liquid are Gaussian distributed, are equivalent to the random phase appr oximation for the static structure factor and to the well-known ideal mode coupling theory (MCT) equations for the dynamics. This finding suggests tha t MCT is a theory of fluid dynamics that becomes exact in a mean-field limi t.