Unstable products from the ozonation of C-60 in solvents

Citation
D. Heymann et F. Cataldo, Unstable products from the ozonation of C-60 in solvents, FUL SCI TEC, 9(1), 2001, pp. 71-76
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
FULLERENE SCIENCE AND TECHNOLOGY
ISSN journal
1064122X → ACNP
Volume
9
Issue
1
Year of publication
2001
Pages
71 - 76
Database
ISI
SICI code
1064-122X(2001)9:1<71:UPFTOO>2.0.ZU;2-8
Abstract
The ozonation of a solution of C-60 in toluene results in the formation of several unstable compounds C60X and C60Y[1-5] which decay completely at roo m temperature within about 1 h. The products are oxides C60O[6,6], C60O2[I] , C60O2[II], and possibly an isomer of C60O3 The transformations are not du e to oxidation by atmospheric oxygen but are spontaneous. The ozonation of a solution of C60O[6,6] in toluene results in the formation of two unstable compounds C(60)Z[1-2] which also decay completely to C60O2[I] and C60O2[II ] It is suggested that all. unstable "parents" are ozonides.