Bb. Karki et al., First principles thermoelasticity of MgSiO3-perovskite: consequences for the inferred properties of the lower mantle, GEOPHYS R L, 28(14), 2001, pp. 2699-2702
Some key thermoelastic properties of MgSiO3-perovskite (pv) have been deter
mined at lower mantle (LM) pressures and temperatures using the quasi-harmo
nic approximation in conjunction with first principles phonon dispersions.
The adiabatic bulk moduli (Ks) of pv and of an assemblage of 80 vol% pv and
20 vol% MgO were obtained along the thermodynamically inferred adiabat and
compared with the seismic counterpart given by the preliminary reference E
arth model (K-PREM) The discrepancy between calculated Ks's and K-PREM in t
he deep LM suggests a super-adiabatic gradient, or subtle changes of compos
ition, or phase, or all beginning at about 1200 km. The Anderson Cruneisen
parameter, delta (S) = (partial derivative lnK(S)/partial derivative ln(P))
(p), was predicted to decrease rapidly with depth (from 2.7 to 1.2 across t
he LM) supporting the thermal origin for the lateral heterogeneities throug
hout most of the LM.