Synthesis and structure of pentaphenyltelluronium salts of perchlorate andtetrakis{3,5-bis(trifluoromethyl)phenyl}borate: Hypervalent onium compounds

Authors
Minoura, M Mukuda, T Sagami, T Akiba, KY
Citation
M. Minoura et al., Synthesis and structure of pentaphenyltelluronium salts of perchlorate andtetrakis{3,5-bis(trifluoromethyl)phenyl}borate: Hypervalent onium compounds, HETEROAT CH, 12(5), 2001, pp. 380-384
Citations number
20
Categorie Soggetti
Chemistry
Journal title
HETEROATOM CHEMISTRY
ISSN journal
10427163 → ACNP
Volume
12
Issue
5
Year of publication
2001
Pages
380 - 384
Database
ISI
SICI code
1042-7163(2001)12:5<380:SASOPS>2.0.ZU;2-Z
Abstract
The reaction of pentaphenyltellurium chloride 2 with silver perchlorate aff orded the pentaphenyltelluronium salt, Ph5Te+ClO4-, (1b), and treatment of 2 with silver triflate and sodium tetakis(3,5-bis(trifluoromethyl)phenyl/bo rate provided Ph5Te+ [3,5-(CF3)(2)C6H3](4)B- (1c), which were isolated as s table yellow solids. X-ray crystallographic analyses of the hypervalent tel luronium salts revealed square-pyramidal geometry around the tellurium, whi ch ave ave examples for penta-substituted main group element compounds. (C) 2001 John Wiley & Sons, Inc.