The change occurring in the photoluminescence spectra and the photolum
inescence excitation spectra during aging of porous-silicon samples in
air and in vacuum has been investigated. It was found that the charac
ter of the photoluminescence changes occurring during aging depends on
the wavelength of the exciting light: In the case of excitation in th
e visible-range band of the luminescence excitation spectrum (lambda(e
xc) > 490 nm) the photoluminescence decreases and in the case of excit
ation in the ultraviolet band it predominantly increases. It is shown
that the two bands of the luminescence excitation spectrum (visible an
d ultraviolet) correspond to two different objects on the surface of t
he porous layer. (C) 1997 American Institute of Physics.