The solar cell which is employed for photovoltaic water electrolysis was fa
bricated by sputter-depositing a-Si:H on Si wafer. The electrolysis was con
ducted by connecting the series-connected solar cell externally to the hydr
ogen and the oxygen evolution electrodes. The conversion efficiency of 3.0%
from the solar to hydrogen chemical energy was obtained and can be expecte
d to be improved further by optimizing the system. (C) 2001 international A
ssociation for Hydrogen Energy. Published by Elsevier Science Ltd. All righ
ts reserved.