The initial stage of formation of oxygen precipitates in silicon is in
vestigated by deep-level transient spectroscopy, selective etching, an
d infrared spectrometry. It is established that the formation of oxyge
n precipitates at T-a = 600-960 degrees C is sustained by the emergenc
e of local zones enriched with interstitial oxygen. As the anneal time
is increased, these zones decrease in size, and the local oxygen conc
entration makes a transition to the SiO2 phase. Hydrostatic pressure a
pplied in the nucleation stage lends to the formation of finer precipi
tates and accelerates the transition to the SiO2 phase. (C) 1997 Ameri
can Institute of Physics.