In order to develop an efficient heating process for the waste slag treatme
nt, the heating behavior of the synthetic CaO-SiO2-FetO slag under microwav
e irradiation was investigated. The heating rate of the slags was found to
vary with the ratio of Fe3+/(Fe2+ + Fe3+) in the slags and the microwave en
ergy was most efficiently absorbed when the value of Fe3+/(Fe2+/Fe3+) was a
round 0.16 with the largest dielectric loss of the slag. Also the hearing r
ate was benefited considerably from the presence of CaFe3O5 and magnetite p
hases in slags that have high value of dielectric loss. When the graphite p
owder was added to the slags, healing rate was drastically increased and th
e larger amount of carbon addition brought the higher value of heating rate
.