Solution properties of trivalent lanthanide trinuclear complexes with ligand 1,3,5-triamino-1,3,5-trideoxy-cis-inositol

Authors
Chapon, D Husson, C Delangle, P Lebrun, C Vottero, PJA
Citation
D. Chapon et al., Solution properties of trivalent lanthanide trinuclear complexes with ligand 1,3,5-triamino-1,3,5-trideoxy-cis-inositol, J ALLOY COM, 323, 2001, pp. 128-132
Citations number
24
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF ALLOYS AND COMPOUNDS
ISSN journal
09258388 → ACNP
Volume
323
Year of publication
2001
Pages
128 - 132
Database
ISI
SICI code
0925-8388(20010712)323:<128:SPOTLT>2.0.ZU;2-E
Abstract
The aqueous complexation reactions of trivalent lanthanide cations with the ligand 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (TACI) have been charact erised using potentiometry, electrospray ionisation mass spectrometry and s olution NMR. Isostructural trinuclear complexes, [Ln(3)(TACIH(-3))(2)](3+), are formed all along the series and their stability constants are extremel y dependent on the cation radius. (C) 2001 Elsevier Science B.V. All rights reserved.