Synthesis and structure of bis(triethanolamine)europium(II) diperchlorate

Authors
Starynowicz, P
Citation
P. Starynowicz, Synthesis and structure of bis(triethanolamine)europium(II) diperchlorate, J ALLOY COM, 323, 2001, pp. 159-163
Citations number
19
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF ALLOYS AND COMPOUNDS
ISSN journal
09258388 → ACNP
Volume
323
Year of publication
2001
Pages
159 - 163
Database
ISI
SICI code
0925-8388(20010712)323:<159:SASOBD>2.0.ZU;2-7
Abstract
The crystal structure of the title compound was determined at 293 and 100 K . The structure contains bis(triethanolamine)europium(II) cations, and perc hlorate anions. The metal ion coordination environment is composed of two N and six O atoms. At room temperature, all triethanolamine molecules are pa rtially disordered. On going to 100 K, the disorder partially disappears, g iving rise to a commensurate modulation of the structure. (C) 2001 Elsevier Science B.V. All rights reserved.