Synthesis and characterization of polynuclear lanthanide aryloxides

Authors
Carretas, J Branco, J Marcalo, J Isolani, P Domingos, A de Matos, AP
Citation
J. Carretas et al., Synthesis and characterization of polynuclear lanthanide aryloxides, J ALLOY COM, 323, 2001, pp. 169-172
Citations number
16
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF ALLOYS AND COMPOUNDS
ISSN journal
09258388 → ACNP
Volume
323
Year of publication
2001
Pages
169 - 172
Database
ISI
SICI code
0925-8388(20010712)323:<169:SACOPL>2.0.ZU;2-J
Abstract
The reactions of europium and ytterbium in liquid ammonia with a solution o f I-naphthol in tetrahydrofuran provide a convenient route to lanthanide ar yloxides. The polymetallic lanthanide complexes [Eu-4(mu -OC10H7)(6)(OC10H7 )(2)(THF)(10)].2THF 1 and [Yb(mu -OC10H7)-(OC10H7)(2)(THF)(MeCN)](2).2MeCN 2 were synthesized and characterized by X-ray diffraction studies. (C) 2001 Elsevier Science B.V. All rights reserved.