Ex situ spectroscopic ellipsometry investigation of the layered structure of polycrystalline diamond thin films grown by electron cyclotron resonance-assisted chemical vapor deposition
S. Gupta et al., Ex situ spectroscopic ellipsometry investigation of the layered structure of polycrystalline diamond thin films grown by electron cyclotron resonance-assisted chemical vapor deposition, J APPL PHYS, 90(3), 2001, pp. 1280-1285
Polycrystalline diamond thin films deposited by electron cyclotron resonanc
e-assisted chemical vapor deposition on Si (111) were investigated using sp
ectroscopic phase-modulated ellipsometry from the near IR to UV range (830-
270 nm). Analysis of the raw ellipsometry data [psi(lambda (i)), Delta(lamb
da (i))] by applying the conventional Bruggeman effective medium theory and
linear regression analysis provided details about the film microstructure:
(i) the multilayer structure and the component layer thickness of the film
s; (ii) the volume fraction of the constituents (sp(3)- and sp(2)- bonded c
arbon) and of voids (f(v)) in the bulk layer (L-2); (iii) the inhomogeneity
of the structure along the growth axis and its variation with the seeding
density; and (iv) the surface roughness layer thickness (d(S)). A simplifie
d three-layer structural model consisting of an interfacial layer, an inter
mediate (or bulk) layer, and a top surface roughness layer has been propose
d that simulates the ellipsometry data reasonably well. The results obtaine
d through ellipsometry modeling, such as surface roughness and overall film
thickness, were compared with those from atomic force microscopy and profi
lometry, respectively, in order to validate the model employed. Typically,
high surface roughness values around 60 nm were found for films grown under
different substrate temperatures and oxygen-to-carbon ratios. It was also
found that a combination of relatively high substrate temperature and O/C r
atio can be used to reduce the surface roughness to around 25 nm. In genera
l, the void fraction (f(v)) of the bulk layer decreases as a function of se
eding density, indicating the formation of a denser film. The sp(2)-bonded
carbon fraction (f(sp)(C)(2)) also varies with the process parameters. Thes
e results (f(v) and f(sp)(2) (C)) for the bulk layer and its behavior with
respect to process parameters are discussed. (C) 2001 American Institute of
Physics.