A theoretical analysis of single-barrier thermionic emission cooling in sem
iconducting materials is performed using Fermi-Dirac statistics. Both maxim
um cooling and coefficient of performance are evaluated. It is shown that t
he performance of a thermionic refrigerator is governed by the same materia
ls factor as thermoelectric devices. For all known materials, single-barrie
r thermionic refrigeration is less effective and less efficient than thermo
electric refrigeration. (C) 2001 American Institute of Physics.