Synthesis, characterization, and glass transition temperature of poly(styrene-b-butyl methacrylate) block copolymers by stable free radical polymerization

Authors
Fernandez-Garcia, M Cuervo-Rodriguez, R Madruga, EL
Citation
M. Fernandez-garcia et al., Synthesis, characterization, and glass transition temperature of poly(styrene-b-butyl methacrylate) block copolymers by stable free radical polymerization, J APPL POLY, 82(1), 2001, pp. 14-21
Citations number
26
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
82
Issue
1
Year of publication
2001
Pages
14 - 21
Database
ISI
SICI code
0021-8995(20011003)82:1<14:SCAGTT>2.0.ZU;2-I
Abstract
The synthesis of controlled polystyrenes with different molecular weights h as been performed in the presence of 1-phenyl-1-(2,2,8,6-tetramethyl-1-pipe ridinyl- oxy)ethane (PETEMPO). The polystyrenes have served as macroinitiat ors for the formation of poly(styrene-b-butyl methacrylate) block copolymer s, Using differential scanning calorimetry (DSC) it has been shown that all black copolymers synthesized do not present phase segregation. (C) 2001 Jo hn Wiley & Sons, Inc.