Preliminary electroanalytical data regarding the electrochemical synthesisof some nitrosoderivatives and complex structure hydroxylamines

Continuing our previous researches regarding the electrochemical behavior o f the nitro derivatives having p-nitrophenileserinol, p-NFS, as main strucu re [3-5], this paper presents the electrochemical behavior of some Schiff b ases, derivatives of p-NFS. in alcoolic phosphate buffer (pH =5), on glassy carbon and mercury electrodes (HMDE and SMDE), Using the electroanalytical data obtained elaborated the electrochemical preparation methodes of the h ydroxilamines (on Hg electrodes) and of the nitrozo derivatives (in "redox" cell). Succesive charge transfer reactions performed directly in solution, allow us to prepare the N-sulfonics derivatives. prouving the existence of the nitrosoderivatives under two monomer and dimer.