Pyrimidinium ylides. IX - The synthesis and the stability of some new pyrimidinium ylides

Citation
Pc. Iuhas et al., Pyrimidinium ylides. IX - The synthesis and the stability of some new pyrimidinium ylides, REV RO CHIM, 46(1), 2001, pp. 55-62
Citations number
17
Categorie Soggetti
Chemistry
Journal title
REVUE ROUMAINE DE CHIMIE
ISSN journal
00353930 → ACNP
Volume
46
Issue
1
Year of publication
2001
Pages
55 - 62
Database
ISI
SICI code
0035-3930(200101)46:1<55:PYI-TS>2.0.ZU;2-4
Abstract
The paper deals with the synthesis of 4-(2-furyl)- and 4-(2-thienyl)pyrimid ines, their quaternization reactions with 2-bromoacetophenones, 2-bromoacet onaphthone and ethyl bromoacetate and the obtaining of 4-(2-furyl)and 4-(2- thienyl)pyrimidinium ylides, by treating the corresponding quaternary salts with bases. The dipyrimidinopyrazinic dimmers were obtained as inactivatio n products of 4-(2-furyl)- and 4-(2-thienyl)pyrimidinium ylides.