Acetylenic hydroperoxides derived from 2e-methyldecahydroquinolin-4-one

Authors
Dikusar, EA Kozlov, NG Moiseichuk, KL
Citation
Ea. Dikusar et al., Acetylenic hydroperoxides derived from 2e-methyldecahydroquinolin-4-one, RUSS J G CH, 71(6), 2001, pp. 921-925
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
6
Year of publication
2001
Pages
921 - 925
Database
ISI
SICI code
1070-3632(200106)71:6<921:AHDF2>2.0.ZU;2-C
Abstract
2e-Methyldecahydroquinolin-4-one was reacted with lithium tert-alkylperoxy acetylides to prepare 4-hydroxy-2e-methyl-4-(2-methyl-2-tert-alkylperoxy-1- butyn-4-yl)decahydroquinolines. The latter readily react with carboxylic ac ids and methyl iodide, affording the corresponding salts.