Ion-molecule reactions of free phenyl cations with diethylamine in the gasphase: Radiochemical study

Authors
Kochina, TA Kalinin, EO Sinotova, EN Ignat'ev, IS Kinebas, AA
Citation
Ta. Kochina et al., Ion-molecule reactions of free phenyl cations with diethylamine in the gasphase: Radiochemical study, RUSS J G CH, 71(6), 2001, pp. 934-938
Citations number
37
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
6
Year of publication
2001
Pages
934 - 938
Database
ISI
SICI code
1070-3632(200106)71:6<934:IROFPC>2.0.ZU;2-P
Abstract
Ion-molecule reactions of free phenyl cations with diethylamine in the gas phase were studied radiochemically. The reaction practically totally follow s the pathway of proton transfer, which occurs in the intermediate complex not only from the incoming cation (C6H5+) but also from the ethyl substitue nt of the amine. Also, products of the reaction of diethylan-dne with benzy ne (C6H4) generated by proton abstraction from the phenyl cation were detec ted.