Ta. Kochina et al., Ion-molecule reactions of free phenyl cations with diethylamine in the gasphase: Radiochemical study, RUSS J G CH, 71(6), 2001, pp. 934-938
Ion-molecule reactions of free phenyl cations with diethylamine in the gas
phase were studied radiochemically. The reaction practically totally follow
s the pathway of proton transfer, which occurs in the intermediate complex
not only from the incoming cation (C6H5+) but also from the ethyl substitue
nt of the amine. Also, products of the reaction of diethylan-dne with benzy
ne (C6H4) generated by proton abstraction from the phenyl cation were detec
ted.