Comparative study of redox reactions in the systems of iron(III) chloride and copper(II) chloride with N,N '-diethylhydroxylamine and 2,4-toluylenediisocyanate

Citation
Gb. Burmakina et al., Comparative study of redox reactions in the systems of iron(III) chloride and copper(II) chloride with N,N '-diethylhydroxylamine and 2,4-toluylenediisocyanate, RUSS J IN C, 46(11), 2001, pp. 1715-1717
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
11
Year of publication
2001
Pages
1715 - 1717
Database
ISI
SICI code
0036-0236(200111)46:11<1715:CSORRI>2.0.ZU;2-R
Abstract
Voltammetry with a stationary platinum electrode in acetonitrile was employ ed to study redox processes occurring in the systems of iron(III) chloride hexahydrate and copper(II) chloride dihydrate with N,N'-diethylhydroxylamin e (DEHA) and 2,3-toluyienediisocyanate (2,4-TDI). The FeCl3. 6H(2)O-DEHA sy stem forms iron(II,III) complexes with nitron. The CuCl2. 2H(2)O-DEHA-2,4-T DI system forms copper(I,II) complexes with nitron and 4,4'-dimethyl-3,3'-d iisocyanatoazobenzene. Variously oxidized iron and copper ions are linked t hrough chloride bridges.