Comparative study of redox reactions in the systems of iron(III) chloride and copper(II) chloride with N,N '-diethylhydroxylamine and 2,4-toluylenediisocyanate

Authors
Burmakina, GB Rubaillo, AI Pavlenko, NI Lukicheva, OV Polezhaeva, IV
Citation
Gb. Burmakina et al., Comparative study of redox reactions in the systems of iron(III) chloride and copper(II) chloride with N,N '-diethylhydroxylamine and 2,4-toluylenediisocyanate, RUSS J IN C, 46(11), 2001, pp. 1715-1717
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
11
Year of publication
2001
Pages
1715 - 1717
Database
ISI
SICI code
0036-0236(200111)46:11<1715:CSORRI>2.0.ZU;2-R
Abstract
Voltammetry with a stationary platinum electrode in acetonitrile was employ ed to study redox processes occurring in the systems of iron(III) chloride hexahydrate and copper(II) chloride dihydrate with N,N'-diethylhydroxylamin e (DEHA) and 2,3-toluyienediisocyanate (2,4-TDI). The FeCl3. 6H(2)O-DEHA sy stem forms iron(II,III) complexes with nitron. The CuCl2. 2H(2)O-DEHA-2,4-T DI system forms copper(I,II) complexes with nitron and 4,4'-dimethyl-3,3'-d iisocyanatoazobenzene. Variously oxidized iron and copper ions are linked t hrough chloride bridges.