Synthesis, X-ray diffraction data, and H-1 and C-13 NMR spectra of N-(N-arylsulfonylimidoyl)-1,4-benzoquinonimines derived from N-aroyl(acetyl)-1,4-benzoquinonimines
Ap. Avdeenko et al., Synthesis, X-ray diffraction data, and H-1 and C-13 NMR spectra of N-(N-arylsulfonylimidoyl)-1,4-benzoquinonimines derived from N-aroyl(acetyl)-1,4-benzoquinonimines, RUSS J ORG, 37(7), 2001, pp. 991-1000
Oxidation of N-(N-arylsulfonylimidoyl)-4-aminophenols gave the correspondin
g N-(N-arylsulfonylimidoyl)-1,4-benzoquinonimines, derivatives of N-aroyl-
and N-acetyl-1,4-benzoquinonimines. The structure of the products was studi
ed by the X-ray diffraction method and H-1 and C-13 NMR spectroscopy. N-(N-
Arylsulfonylimidoyl)-1,4-benzoquinonimines were found to undergo fast (on t
he NMR time scale) Z,E isomerization about the C=N bond in the quinonimine
fragment. N-(N-Arylsulfonylacetimidoyl)-1,4-benzoquinonimines in solution g
ive rise to dynamic Z,E-isomerization with respect to the C=N bond in the N
-arylsulfonylacetimidoyl fragment.