A review of recent results on the complex refractive index determination of
oriented poly(p-phenylene-vinylene) (PPV) by polarized near-normal-inciden
ce reflectance, transmittance and ellipsometry measurements is presented. I
n particular, the new experimental data obtained for highly stretch-oriente
d films of PPV and the results of correlated quantum-chemical calculations
on the same polymer will be reported and discussed with the purpose of clar
ify the controversial assignment of the electronic transitions of PPV and i
ts derivatives. (C) 2001 Elsevier Science B.V. All rights reserved.