Synthesis of silylated beta-enaminones and applications to the synthesis of silyl heterocycles

Authors
Calvo, LA Gonzalez-Nogal, AM Gonzalez-Ortega, A Sanudo, MC
Citation
La. Calvo et al., Synthesis of silylated beta-enaminones and applications to the synthesis of silyl heterocycles, TETRAHEDR L, 42(51), 2001, pp. 8981-8984
Citations number
31
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
51
Year of publication
2001
Pages
8981 - 8984
Database
ISI
SICI code
0040-4039(200112)42:51<8981:SOSBAA>2.0.ZU;2-W
Abstract
Silyl beta -enaminones have been synthesized by reductive cleavage of sityl isoxazoles. These versatile synthons bearing the silyl group in different p ositions of the enamino ketonic system are of great interest in the constru ction of a variety of penta- and hexaheterocycles. which, in general, retai n the silyl group attached at the ring or in a side chain. (C) 2001 Elsevie r Science Ltd, All rights reserved.