Highly active salted low-valent titanium reagents for various SET induced reactions

Authors
Rele, S Chattopadhyay, S Nayak, SK
Citation
S. Rele et al., Highly active salted low-valent titanium reagents for various SET induced reactions, TETRAHEDR L, 42(51), 2001, pp. 9093-9095
Citations number
26
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
51
Year of publication
2001
Pages
9093 - 9095
Database
ISI
SICI code
0040-4039(200112)42:51<9093:HASLTR>2.0.ZU;2-N
Abstract
External addition of inorganic salts (Group I and II metal halides) to the preformed low-valent titanium reagent A (TiCl3-Li-THF) dramatically enhance d its activity. The new reagents were used to carry out various SET reactio ns including McMurry's olefination at a faster rate even at ambient tempera ture. (C) 2001 Published by Elsevier Science Ltd.