A laser probing technique has been applied to a stored ion beam of Xe to study collisional destruction of metastable states as well as coll
isional excitation by the residual gas in the storage ring. The result
s are of great importance for the evaluation of lifetime measurements
of metastable states in storage rings. For the states studied in Xe+,
it was found that neither of the two processes caused systematic error
s in the lifetime determination. It is also shown that the method can
yield partial cross sections for collisional excitation.