NONLINEAR QUANTUM DYNAMICS OF STRONG VIBRATION - RELAXATION JUMPS ANDPHONON BURSTS

Citation
V. Hizhnyakov et D. Nevedrov, NONLINEAR QUANTUM DYNAMICS OF STRONG VIBRATION - RELAXATION JUMPS ANDPHONON BURSTS, Zeitschrift für physikalische Chemie, 201, 1997, pp. 301-315
Citations number
29
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
ISSN journal
09429352
Volume
201
Year of publication
1997
Part
1
Pages
301 - 315
Database
ISI
SICI code
0942-9352(1997)201:<301:NQDOSV>2.0.ZU;2-8
Abstract
We examine the quantum decay of localized vibrations in an anharmonic crystal lattice. The theory which describes two-phonon anharmonic rela xation can be applied both to local modes associated with a substituti onal impurity and to intrinsic local modes (ILM) in perfect lattices. It is found that for sufficiently high initial excitations the relaxat ion of vibrations is non-exponential, it demonstrates explosion-like b ehavior at specific stages of evolution. The course of the relaxation is determined by the initial value of energy, temperature, direction o f vibrations. As an example we present the results of calculations of the relaxation of an odd local (impurity) mode in a simple cubic latti ce and discuss the influence of quantum fluctuations on the stability of the ILM in a one-dimensional monatomic chain.