S. Kroger et Apf. Turner, SOLVENT-RESISTANT CARBON ELECTRODES SCREEN-PRINTED ONTO PLASTIC FOR USE IN BIOSENSORS, Analytica chimica acta, 347(1-2), 1997, pp. 9-18
A three electrode design using solvent resistant materials is reported
, enabling the production of screen printed electrodes for use in bios
ensor applications involving water-miscible organic solvents. Heat sta
bilised polyester sheets were used as base materials in combination wi
th carbon basal tracks and an epoxy-based polymer protective coating.
The new electrodes avoid problems with solvent induced baseline shifts
displayed by conventional screen-printed electrodes. The material for
the underlying basal track has been changed from silver to carbon ink
to reduce the number of materials involved in the production and avoi
d possible interferences. In addition, the design is readily applied i
n biosensor applications. Different methods for the incorporation of a
rhodium catalyst are discussed. The application of the electrode syst
em modified with the rhodium catalyst for the amperometric detection o
f hydrogen peroxide in different concentrations of methanol, isopropan
ol and ethanol is demonstrated.