A correlation is shown to exist between the cathodic polarizability of
CT3 steel in 0.05 N KCl solution at 22 degrees C under the films that
contain inhibitors based on thirty-one substituted derivatives of ben
zylidene-aniline, on the one hand, and the basicity of inhibitors and
the electron donor and acceptor properties of the substituents, on the
other hand. In the electronic effect of substituents on the reaction
center of inhibitors, the contributions of the inductive effect and th
e mesomeric conjugation are estimated.