SOME KINETIC ASPECTS OF THE HIGH-TEMPERATURE ANHYDROUS FECL2 HYDROLYSIS REACTION

Authors
VILCU R COSEAC T OANCEA D
Citation
R. Vilcu et al., SOME KINETIC ASPECTS OF THE HIGH-TEMPERATURE ANHYDROUS FECL2 HYDROLYSIS REACTION, Revue Roumaine de Chimie, 42(2), 1997, pp. 93-97
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
42
Issue
2
Year of publication
1997
Pages
93 - 97
Database
ISI
SICI code
0035-3930(1997)42:2<93:SKAOTH>2.0.ZU;2-7
Abstract
The present paper deals with the kinetics of anhydrous FeCl2 hydrolysi s in gas phase, the hydrogen generating step in the thermochemical cyc les of Fe-Cl family. The temperature and water feed flow rate dependen ce on the reaction rate, within the range 853-893 K and 5-16 cm(3)/s i s presented. The initial reaction rates were measured, a formal kineti c equation was derived and the kinetic parameters were estimated.