PHOSPHORUS MONOXIDE AS A TERMINAL LIGAND

Authors
JOHNSON MJA ODOM AL CUMMINS CC
Citation
Mja. Johnson et al., PHOSPHORUS MONOXIDE AS A TERMINAL LIGAND, Chemical communications, (16), 1997, pp. 1523-1524
Citations number
35
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1997
Pages
1523 - 1524
Database
ISI
SICI code
1359-7345(1997):16<1523:PMAATL>2.0.ZU;2-X
Abstract
Dimethyldioxirane oxidation of phosphide PMo[N(R)Ar](3) [R = C(CD3)(2) Me, Ar = C6H3Me2-3,5] efficiently provides (OP)Mo[N(R)Ar](3), a comple x shown by X-ray crystallography to contain a terminal phosphorus mono xide ligand, and which reacts with dimethylzirconocene to give additio n of a Zr-Me bond across the phosphoryl moiety.