VIBRATIONAL PROPERTIES OF ETHYLTITANIUM TRICHLORIDE AND ITS 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE ADDUCT - CHARACTERIZATION OF ISOLATED NU(C-H) MODES AND IMPLICATIONS FOR AGOSTIC BONDING

Authors
MCGRADY GS DOWNS AJ HAALAND A SCHERER W MCKEAN DC
Citation
Gs. Mcgrady et al., VIBRATIONAL PROPERTIES OF ETHYLTITANIUM TRICHLORIDE AND ITS 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE ADDUCT - CHARACTERIZATION OF ISOLATED NU(C-H) MODES AND IMPLICATIONS FOR AGOSTIC BONDING, Chemical communications, (16), 1997, pp. 1547-1548
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1997
Pages
1547 - 1548
Database
ISI
SICI code
1359-7345(1997):16<1547:VPOETA>2.0.ZU;2-F
Abstract
The IR spectra of normal and specifically deuteriated [CH3CH2TiCl3] sh ow that coordination by Me2PCH2CH2PMe2 (dmpe) results in an unusually low stretching frequency for one of the beta-C-H bonds in the ethyltit anium fragment; the results are analysed for their relevance to the bo nding in the beta-agostic unit in the light of quantum chemical calcul ations.