SYNTHESIS OF ALPHA,BETA-UNSATURATED SELENOAMIDES BY THE CONDENSATION REACTION OF LITHIUM ENESELENOLATE GENERATED FROM SELENOACETAMIDE WITH ALDEHYDES

Authors
MURAI T EZAKA T ICHIMIYA T KATO S
Citation
T. Murai et al., SYNTHESIS OF ALPHA,BETA-UNSATURATED SELENOAMIDES BY THE CONDENSATION REACTION OF LITHIUM ENESELENOLATE GENERATED FROM SELENOACETAMIDE WITH ALDEHYDES, Synlett, (7), 1997, pp. 775
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
7
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):7<775:SOASBT>2.0.ZU;2-A
Abstract
The reaction of lithium eneselenolate generated from selenoacetamide a nd LDA with aldehydes gave alpha,beta-unsaturated selenoamides in good to high yields. The successive addition of n-butyllithium and 3-bromo -1-propene to alpha,beta-unsaturated selenoamide 3a gave selenoamide 7 with high selectivity.