SYNTHESIS OF AN AXIALLY DISSYMMETRIC BIPHENYLCARBOXYLATE LIGAND, BDME, AND ASYMMETRIC CYCLOPROPANATION OF OLEFINS WITH DIAZOACETATE CATALYZED BY ITS DIRHODIUM(II) COMPLEX

Authors
ISHITANI H ACHIWA K
Citation
H. Ishitani et K. Achiwa, SYNTHESIS OF AN AXIALLY DISSYMMETRIC BIPHENYLCARBOXYLATE LIGAND, BDME, AND ASYMMETRIC CYCLOPROPANATION OF OLEFINS WITH DIAZOACETATE CATALYZED BY ITS DIRHODIUM(II) COMPLEX, Synlett, (7), 1997, pp. 781
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
7
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):7<781:SOAADB>2.0.ZU;2-6
Abstract
An axially dissymmetric biphenylcarboxylate ligand, BDME (4), has been newly designed end prepared. The dirhodium(II) complex (1) of (4) pro ved to be an excellent catalyst in asymmetric cyclopropanation of styr ene with d-menthyl diazoacetate affording d-menthyl cis-2-phenyl-cyclo propane-1-carboxylate of 99% de.