EFFICIENT CONDITIONS FOR THE PALLADIUM(II) MEDIATED COUPLING OF ORGANOSTANNANES - THE SYNTHESIS OF 1,3-DIENES, 1,4-DIENES, 1,3-DIYNES AND BIPHENYLS

Authors
ALCARAZ L TAYLOR RJK
Citation
L. Alcaraz et Rjk. Taylor, EFFICIENT CONDITIONS FOR THE PALLADIUM(II) MEDIATED COUPLING OF ORGANOSTANNANES - THE SYNTHESIS OF 1,3-DIENES, 1,4-DIENES, 1,3-DIYNES AND BIPHENYLS, Synlett, (7), 1997, pp. 791
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
7
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):7<791:ECFTPM>2.0.ZU;2-K
Abstract
Convenient conditions are described for the preparation of 1,3-dienes by vinylstannane homocoupling using palladium(II)catalysis with oxygen (or air) for Pd(0)/Pd(II) reoxidation; related home-couplings, and cr oss-coupling reactions with allylstannane, are used to obtain 1,3-diyn es, biaryls and 1,4-dienes.