DIAZO ESTERS ADDITION TO TRIFLUOROPYRUVAMIDES - NEW ACCESS TO HIGHLY FUNCTIONALIZED TRIFLUOROMETHYL EPOXIDES AND DIAZO-COMPOUNDS

Authors
ELKAIM L OLLIVIER C
Citation
L. Elkaim et C. Ollivier, DIAZO ESTERS ADDITION TO TRIFLUOROPYRUVAMIDES - NEW ACCESS TO HIGHLY FUNCTIONALIZED TRIFLUOROMETHYL EPOXIDES AND DIAZO-COMPOUNDS, Synlett, (7), 1997, pp. 797
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
7
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):7<797:DEATT->2.0.ZU;2-5
Abstract
Trifluoropyruvamides in their hydrated form readily react with diazo e aters affording new trifluoromethyl epoxides. Activating the pyruvamid e with trifluoroacetic anhydride leads to a complete change in selecti vity with the formation of a new diazo compound.