SYNTHESIS OF NEW TRIALKYLSILYLMETHYLOXAZINONES VIA INTRAMOLECULAR TRAPPING OF BETA-SILYL CARBOCATIONS BY AN N-BOC GROUP

Authors
BROCHERIEUXLANOY S DHIMANE H POUPON JC VANUCCI C LHOMMET G
Citation
S. Brocherieuxlanoy et al., SYNTHESIS OF NEW TRIALKYLSILYLMETHYLOXAZINONES VIA INTRAMOLECULAR TRAPPING OF BETA-SILYL CARBOCATIONS BY AN N-BOC GROUP, Journal of the Chemical Society. Perkin transactions. I, (15), 1997, pp. 2163-2165
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
15
Year of publication
1997
Pages
2163 - 2165
Database
ISI
SICI code
0300-922X(1997):15<2163:SONTVI>2.0.ZU;2-X
Abstract
N-Boc amino ethers la-e when treated with allyltrialkylsilanes in the presence of TiCl4 afford the expected allylation compounds 2a-e and/or the unprecedented silylated oxazinones 3a-e or 4a-e.