REARRANGEMENT OF BICYCLO[3.2.0]HEPTYL PRECURSORS TO THE 7-NORBORNYL CATION IN THE CRYOGENIC SBF5 MATRIX

Citation
M. Mesic et al., REARRANGEMENT OF BICYCLO[3.2.0]HEPTYL PRECURSORS TO THE 7-NORBORNYL CATION IN THE CRYOGENIC SBF5 MATRIX, Perkin transactions. 2, (6), 1994, pp. 1135-1137
Citations number
25
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
03009580
Issue
6
Year of publication
1994
Pages
1135 - 1137
Database
ISI
SICI code
0300-9580(1994):6<1135:ROBPTT>2.0.ZU;2-I
Abstract
The first direct observation by IR spectroscopy in the cryogenic SbF5 matrix was made of the rearrangement of 2- and 3-chlorobicyclo[3.2.0]h eptanes (3) and (4), respectively, to the 7-norbornyl cation 1 and its subsequent transformation into the 2-norbornyl cation 5.