THE SYNTHESES, ELECTROCHEMISTRY AND MAGNETISM OF SOME PARAMAGNETIC METALLOMACROCYCLES CONTAINING MOLYBDENUM(V) CENTERS

Authors
BERRIDGE TE JONES CJ
Citation
Te. Berridge et Cj. Jones, THE SYNTHESES, ELECTROCHEMISTRY AND MAGNETISM OF SOME PARAMAGNETIC METALLOMACROCYCLES CONTAINING MOLYBDENUM(V) CENTERS, Polyhedron, 16(20), 1997, pp. 3695-3698
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
20
Year of publication
1997
Pages
3695 - 3698
Database
ISI
SICI code
0277-5387(1997)16:20<3695:TSEAMO>2.0.ZU;2-K
Abstract
The reactions between [Mo(=O){HB(3,5-Me(2)pz(3)}Cl-2] and the bifuncti onal ligands 1,3-(HO)(2)C6H4 (1H(2)), 1,3-(HS)(2)C6H4 (2H(2)) 2,7-(HO) (2)C10H6 (3H(2)) and 4,4'-{(HO)C6H4}(2)CH2 (4H(2)) afford the metallom acrocycles. [Mo(=O){HB(3,5-Me(2)pz)(3)}X](2). (X = 1,2,3 and 4) and [M o(=O){HB(3,5-Me(2)pz)(3)}X](3) (X = 1, 3 and 4). Electrochemical studi es provide evidence for the presence of strongly interacting metal cen tres in the resorcinol bridged species. (C) 1997 Elsevier Science Ltd.