RADICAL TRANSLOCATION REACTIONS ACROSS AMIDES - 1,5-HYDROGEN-TRANSFERREACTIONS OF O-IODOBENZAMIDES AND N-(O-IODOBENZYL) AMIDES

Authors
CURRAN DP LIU HT
Citation
Dp. Curran et Ht. Liu, RADICAL TRANSLOCATION REACTIONS ACROSS AMIDES - 1,5-HYDROGEN-TRANSFERREACTIONS OF O-IODOBENZAMIDES AND N-(O-IODOBENZYL) AMIDES, Journal of the Chemical Society. Perkin transactions. I, (11), 1994, pp. 1377-1393
Citations number
79
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
11
Year of publication
1994
Pages
1377 - 1393
Database
ISI
SICI code
0300-922X(1994):11<1377:RTRAA->2.0.ZU;2-H
Abstract
Radicals derived from N,N-disubstituted o-iodobenzamides undergo rapid 1.5-hydrogen-transfer reactions. The regioselectivity of these reacti ons is coupled to the rotamer population of the starting iodobenzamide . and the products vary with changing amide substituents. Related 1,5- hydrogen-transfer reactions are observed for N-alkyl-N-(o-iodobenzyl)- benzamides and -acetamides.